Production Method 1

106-37-6

880-68-2

Reaction Conditions

1.1 Reagents: Triisopropyl phosphite Catalysts: Tetrakis(triphenylphosphine)palladium ;  2 h, 120 °C; 3 d, 200 °C

Reference

Enhancement of Proton Conductivity in Nonporous Metal-Organic Frameworks: The Role of Framework Proton Density and Humidity

Pili, Simona; et al, Chemistry of Materials, 2018, 30(21), 7593-7602

Production Method 2

106-37-6

880-68-2

Reaction Conditions

1.1 Reagents: Triethyl phosphite ,  Nickel bromide Solvents: 1,3-Diisopropylbenzene ;  6 h, rt → 160 °C; 160 °C → 180 °C; 24 h, 180 °C; 180 °C → 120 °C; 48 h, > rt
1.2 Reagents: Hydrochloric acid Solvents: Water ;  110 °C

Reference

Organic-Inorganic Hybrids Assembled from Lanthanide and 1,4-Phenylenebis(phosphonate)

Amghouz, Zakariae; et al, Crystal Growth & Design, 2011, 11(12), 5289-5297

Production Method 3

21267-14-1

880-68-2

Reaction Conditions

1.1 Reagents: Bromotrimethylsilane Solvents: Dichloromethane ;  1 min, rt; 4 h, rt; rt → 0 °C
1.2 Reagents: Water ;  0 °C

Reference

Efficient energy and electron transfer between donor and acceptor chromophores in aluminophosphate hybrid materials

Lo, Chih-Yuan; et al, Journal of the Chinese Chemical Society (Taipei, 2010, 57, 539-546

Production Method 4

21267-14-1

880-68-2

Reaction Conditions

1.1 Reagents: Hydrochloric acid Solvents: Water ;  reflux
2.1 Reagents: Hydrochloric acid Solvents: Water ;  reflux

Reference

Molecular Design of Bisphosphonates To Adjust Their Reactivity toward Metal Sources for the Surfactant-Assisted Synthesis of Mesoporous Films

Kimura, Tatsuo, Angewandte Chemie, 2017, 56(43), 13459-13463

Production Method 5

880-68-2

18917-91-4

880-68-2

Reaction Conditions

1.1 Reagents: Sodium hydroxide Solvents: Water ;  pH 5, rt

Reference

Efficient energy and electron transfer between donor and acceptor chromophores in aluminophosphate hybrid materials

Lo, Chih-Yuan; et al, Journal of the Chinese Chemical Society (Taipei, 2010, 57, 539-546

Production Method 6

880-68-2

880-68-2

Reaction Conditions

1.1 Reagents: Aluminum chloride Solvents: Acetone ,  Water ;  5 d, 210 °C

Reference

Reversible Dehydration Behavior Reveals Coordinatively Unsaturated Metal Sites in Microporous Aluminum Phosphonates

Kinnibrugh, Tiffany L.; et al, Crystal Growth & Design, 2014, 14(10), 4976-4984

Production Method 7

106-37-6

880-68-2

Reaction Conditions

1.1 Catalysts: Nickel dichloride ;  30 min, 150 °C
1.2 4 h, 150 °C; 8 h, 150 °C; 150 °C → rt
2.1 Reagents: Bromotrimethylsilane Solvents: Dichloromethane ;  1 min, rt; 4 h, rt; rt → 0 °C
2.2 Reagents: Water ;  0 °C

Reference

Efficient energy and electron transfer between donor and acceptor chromophores in aluminophosphate hybrid materials

Lo, Chih-Yuan; et al, Journal of the Chinese Chemical Society (Taipei, 2010, 57, 539-546

1,4-Benzenebisphosphonic Acid Raw materials

• 1,4-Dibromobenzene
• 1,4-Benzenebisphosphonic Acid
• 1,4-Bis(diethoxyphosphoryl)benzene
• Aluminum L-Lactate

1,4-Benzenebisphosphonic Acid Preparation Products

• 1,4-Benzenebisphosphonic Acid (880-68-2)

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• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Benzene and substituted derivatives
• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives
• Material Chemicals Electrical Materials

• 642471-55-4(Phosphonic acid, 2-anthracenyl-)
• 75406-75-6(Phosphonic acid, P-phenyl-, titanium(4+) salt (2:1))
• 24391-19-3(Phosphonic acid,P-phenyl-, calcium salt (1:1))
• 50862-86-7(Phosphonic acid, P-phenyl-, zinc salt (1:))
• 69031-88-5(Phosphonic acid, P-phenyl-, zirconium(4+) salt (2:1))
• 75406-86-9(Phosphonic acid, phenyl-, uranium(4+) salt (2:1))
• 75406-80-3(Phosphonic acid, phenyl-, cerium(4+) salt (2:1) (9CI))
• 1571-33-1(Phenylphosphonic acid)
• 75406-79-0(Phosphonic acid, phenyl-, thorium(4+) salt (2:1) (9CI))
• 25148-85-0(Sodium phenylphosphonate)