Production Method 1

858841-53-9

858841-53-9

2247769-22-6

Reaction Conditions

1.1 Reagents: Trifluoromethanesulfonic acid Solvents: Acetic acid ;  5 min, rt
1.2 Reagents: Sodium peroxoborate ;  30 min, rt; 20 h, 50 °C
2.1 Reagents: Boron trifluoride etherate Solvents: Acetonitrile ,  Dichloromethane ;  3 h, -78 °C

Reference

The Coming of Age in Iodane-Guided ortho-C-H Propargylation: From Insight to Synthetic Potential

Izquierdo, Susana ; et al, Chemistry - A European Journal, 2018, 24(58), 15517-15521

Production Method 2

625-95-6

858841-53-9

202865-85-8

888214-21-9

Reaction Conditions

1.1 Reagents: N-Bromosuccinimide Catalysts: Methylium, triphenyl-, tetrafluoroborate(1-) (1:1) Solvents: Acetonitrile ,  Dichloromethane ;  rt
1.2 Reagents: Water

Reference

Carbocation Catalyzed Bromination of Alkyl Arenes, a Chemoselective sp3 vs. sp2 C-H functionalization.

Ni, Shengjun; El Remaily, Mahmoud Abd El Aleem Ali Ali; Franzen, Johan, Advanced Synthesis & Catalysis, 2018, 360(21), 4197-4204

Production Method 3

53078-85-6

858841-53-9

Reaction Conditions

1.1 Reagents: Sodium nitrite ,  Hydrochloric acid ,  Potassium iodide Solvents: Water

Reference

Ruthenium-Catalyzed Cycloisomerization of 2,2'-Diethynyl- biphenyls Involving Cleavage of a Carbon-Carbon Triple Bond

Matsuda, Takanori ; et al, Chemistry - A European Journal, 2016, 22(6), 1941-1943

Production Method 4

13361-64-3

858841-53-9

2247769-22-6

Reaction Conditions

1.1 Reagents: Boron trifluoride etherate Solvents: Acetonitrile ,  Dichloromethane ;  3 h, -78 °C

Reference

The Coming of Age in Iodane-Guided ortho-C-H Propargylation: From Insight to Synthetic Potential

Izquierdo, Susana ; et al, Chemistry - A European Journal, 2018, 24(58), 15517-15521

1-Bromo-2-iodo-4-methylbenzene Raw materials

• 2-Bromo-5-methylaniline
• 3-Iodotoluene
• trimethyl(prop-2-ynyl)silane
• 1-Bromo-2-iodo-4-methylbenzene

1-Bromo-2-iodo-4-methylbenzene Preparation Products

• 1-Bromo-2-iodo-4-methyl-3-(2-propyn-1-yl)benzene (2247769-22-6)
• 2-Bromo-5-iodotoluene (202865-85-8)
• 2-Bromo-1-iodo-3-methylbenzene (888214-21-9)
• 1-Bromo-2-iodo-4-methylbenzene (858841-53-9)

• 1. Fast-pulsing NMR techniques for the detection of weak interactions: successful natural abundance probe of hydrogen bonds in peptides?
  Amandine Altmayer-Henzien,Valérie Declerck,David J. Aitken,Ewen Lescop,Denis Merlet,Jonathan Farjon Org. Biomol. Chem., 2013,11, 7611-7615
• 2. Enabling shape memory and healable effects in a conjugated polymer by incorporating siloxane via dynamic imine bond?
  Yaling Zhang,Chunhui Dai,Shiwei Zhou,Bin Liu Chem. Commun., 2018,54, 10092-10095
• 3. Excellent peroxidase mimicking property of CuO/Pt nanocomposites and their application as an ascorbic acid sensor?
  Xinhuan Wang,Shuangfei Cai,Cui Qi Analyst, 2017,142, 2500-2506
• 4. Excellent electrochemical performance of LiFe0.4Mn0.6PO4 microspheres produced using a double carbon coating process?
  Yong Ping Huang,Tao Tao,Zheng Chen,Wei Han,Ying Wu,Chunjiang Kuang,Shaoxiong Zhou,Ying Chen J. Mater. Chem. A, 2014,2, 18831-18837
• 5. Exciting clusters, what does off-resonance actually mean??
  Goonay Yousefalizadeh,Shideh Ahmadi,Nicholas J. Mosey,Kevin G. Stamplecoskie Nanoscale, 2021,13, 242-252

• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Halobenzenes Iodobenzenes
• Solvents and Organic Chemicals Organic Compounds Hydrocarbons

• 175278-10-1(3,5-Dibromo-4-iodotoluene)
• 116632-38-3(3-Bromo-5-iodotoluene)
• 869500-07-2(1-Bromo-2-iodo-3-methylbenzene)
• 1006715-27-0(4-Bromo-3-iodobenzonitrile)
• 583-55-1(2-Bromoiodobenzene)
• 533-55-1(2-Bromo-iodobenzene)
• 71838-98-7(2-Bromo-1-iodo-4-methylbenzene)
• 71838-95-4(2-Bromo-1-iodo-4-methylbenzene)
• 888214-21-9(2-Bromo-1-iodo-3-methylbenzene)
• 71838-16-9(3-Bromo-4-iodotoluene)