Production Method 1

13361-64-3

2247769-22-6

858841-53-9

Reaction Conditions

1.1 Reagents: Boron trifluoride etherate Solvents: Acetonitrile ,  Dichloromethane ;  3 h, -78 °C

Reference

The Coming of Age in Iodane-Guided ortho-C-H Propargylation: From Insight to Synthetic Potential

Izquierdo, Susana ; et al, Chemistry - A European Journal, 2018, 24(58), 15517-15521

Production Method 2

858841-53-9

2247769-22-6

858841-53-9

Reaction Conditions

1.1 Reagents: Trifluoromethanesulfonic acid Solvents: Acetic acid ;  5 min, rt
1.2 Reagents: Sodium peroxoborate ;  30 min, rt; 20 h, 50 °C
2.1 Reagents: Boron trifluoride etherate Solvents: Acetonitrile ,  Dichloromethane ;  3 h, -78 °C

Reference

The Coming of Age in Iodane-Guided ortho-C-H Propargylation: From Insight to Synthetic Potential

Izquierdo, Susana ; et al, Chemistry - A European Journal, 2018, 24(58), 15517-15521

1-Bromo-2-iodo-4-methyl-3-(2-propyn-1-yl)benzene Raw materials

• trimethyl(prop-2-ynyl)silane
• 1-Bromo-2-iodo-4-methylbenzene

1-Bromo-2-iodo-4-methyl-3-(2-propyn-1-yl)benzene Preparation Products

• 1-Bromo-2-iodo-4-methyl-3-(2-propyn-1-yl)benzene (2247769-22-6)
• 1-Bromo-2-iodo-4-methylbenzene (858841-53-9)

• 1. Establishing plasmon contribution to chemical reactions: alkoxyamines as a thermal probe?
  Olga Guselnikova,Gérard Audran,Jean-Patrick Joly,Andrii Trelin,Evgeny V. Tretyakov,Vaclav Svorcik,Oleksiy Lyutakov,Sylvain R. A. Marque Chem. Sci., 2021,12, 4154-4161
• 2. Fe(iii)-mediated isomerization of α,α-diarylallylic alcohols to ketones via radical 1,2-aryl migration?
  Ziyang Deng,Changwei Chen,Sunliang Cui RSC Adv., 2016,6, 93753-93755
• 3. Dissociative electron attachment to HGaF4 Lewis–Br?nsted superacid
  Marcin Czapla,Jack Simons Phys. Chem. Chem. Phys., 2018,20, 21739-21745
• 4. Evolution of dealloying induced strain in nanoporous gold crystals?
  Ross Harder,David C. Dunand,Ian McNulty Nanoscale, 2017,9, 5686-5693
• 5. Evidence of CO2 molecule acting as an electron acceptor on a nanoporous metal–organic-framework MIL-53 or Cr3+(OH)(O2C–C6H4–CO2)?
  Alexandre Vimont,Arnaud Travert,Philippe Bazin,Jean-Claude Lavalley,Marco Daturi,Christian Serre,Gérard Férey,Sandrine Bourrelly,Philip L. Llewellyn Chem. Commun., 2007, 3291-3293

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