Production Method 1

2267-47-2

85068-30-0

123184-17-8

Reaction Conditions

1.1 Reagents: Potassium hydroxide Catalysts: Iridium(1+), chloro[2-(4,5-dihydro-1H-imidazol-2-yl-κN3)-5-methoxypyridine-κN][(… Solvents: Water ;  10 h, 80 °C

Reference

Iridium Complexes as Efficient Catalysts for Construction of α-Substituted Ketones via Hydrogen Borrowing of Alcohols in Water

Luo, Nianhua; Zhong, Yuhong; Wen, Huiling; Shui, Hongling; Luo, Renshi, European Journal of Organic Chemistry, 2021, 2021(9), 1355-1364

Production Method 2

4637-24-5

364-83-0

85068-30-0

Reaction Conditions

1.1 24 h, 120 °C
1.2 Reagents: Hydrogen Catalysts: Palladium Solvents: Ethanol ;  12 h, rt

Reference

DMF Dimethyl Acetal as Carbon Source for α-Methylation of Ketones: A Hydrogenation-Hydrogenolysis Strategy of Enaminones

Borah, Ashwini; Goswami, Limi; Neog, Kashmiri; Gogoi, Pranjal, Journal of Organic Chemistry, 2015, 80(9), 4722-4728

Production Method 3

85068-30-0

Reaction Conditions

1.1 Catalysts: Aluminum chloride

Reference

Design, synthesis and antifungal activity of novel triazole derivatives with piperazine side chain

Xu, Bo; Shi, Yuan; Zhang, Wan-nian; Sheng, Chun-quan, Yaoxue Shijian Zazhi, 2013, 31(3), 176-180

2',4'-Difluoropropiophenone Raw materials

• (dimethoxymethyl)dimethylamine
• 2,4-Difluoroacetophenone
• 1-(2,4-difluorophenyl)ethan-1-ol

2',4'-Difluoropropiophenone Preparation Products

• 2',4'-Difluoropropiophenone (85068-30-0)
• 1-(2,4-difluorophenyl)prop-2-en-1-one (123184-17-8)

• 1. Fe3O4 nanosphere@microporous organic networks: enhanced anode performances in lithium ion batteries through carbonization?
  Byungho Lim,Jaewon Jin,Jin Yoo,Seung Yong Han,Kyeongyeol Kim,Sungah Kang,Nojin Park,Sang Moon Lee,Hae Jin Kim,Seung Uk Son Chem. Commun., 2014,50, 7723-7726
• 2. Embedding heteroatoms: an effective approach to create porphyrin-based functional materials
  Norihito Fukui,Keisuke Fujimoto,Hideki Yorimitsu,Atsuhiro Osuka Dalton Trans., 2017,46, 13322-13341
• 3. Evolution study of photo-synthesized gold nanoparticles by spectral deconvolution model: a quantitative approach
  Chung-Sung Yang,Mong-Shian Shih,Fang-Yi Chang New J. Chem., 2006,30, 729-735
• 4. Distinction of trans–cis photoisomers with comparable optical properties in multiple-state photochromic systems – examining a molecule with three azobenzenes via in situ irradiation NMR spectroscopy?
  Jonas Kind,Lukas Kaltschnee,Martin Leyendecker,Christina M. Thiele Chem. Commun., 2016,52, 12506-12509
• 5. Fe/S-Catalyzed synthesis of 2-benzoylbenzoxazoles and 2-quinolylbenzoxazoles via redox condensation of o-nitrophenols with acetophenones and methylquinolines?
  Thi Thu Tram Nguyen,Thanh Binh Nguyen Org. Biomol. Chem., 2021,19, 6015-6020

• Solvents and Organic Chemicals Organic Compounds Organic oxygen compounds Organooxygen compounds Ketones
• Solvents and Organic Chemicals Organic Compounds Organic oxygen compounds Organooxygen compounds Carbonyl compounds Ketones
• Solvents and Organic Chemicals Organic Compounds cyanides/Cyanides

• 29112-90-1(2',5'-Difluoropropiophenone)
• 446-22-0(2-Fluoropropiophenone)
• 220141-69-5(2',4',6'-Trifluoropropiophenone)
• 142472-18-2(1,3-Propanedione,1,3-bis(2,4-difluorophenyl)-)
• 95727-77-8(1-Butanone,1-(2,6-difluorophenyl)-)
• 77294-82-7(1-(2-fluorophenyl)-2-phenylethan-1-one)
• 654673-34-4( )
• 465514-59-4(Ethanone,1-(2,6-difluorophenyl)-2-phenyl-)
• 85068-31-1(2',6'-Difluoropropiophenone)
• 64287-17-8(1-(2,4-difluorophenyl)butane-1,3-dione)