Cas no 849062-23-3 (3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid)
3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid is a boronic acid derivative widely utilized in Suzuki-Miyaura cross-coupling reactions due to its stability and reactivity. The presence of the bromo and methoxybenzyloxy substituents enhances its versatility in forming complex biaryl structures, making it valuable in pharmaceutical and materials science research. The boronic acid moiety facilitates efficient transmetalation with palladium catalysts, while the methoxybenzyloxy group provides steric and electronic modulation for selective coupling. This compound is particularly useful in synthesizing intermediates for drug discovery and functional materials. Its well-defined structure and consistent purity ensure reliable performance in demanding synthetic applications.
849062-23-3 structure
Product Name:3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid
CAS No:849062-23-3
MF:C15H16BBrO4
MW:351.000144004822
MDL:MFCD06411315
CID:716693
PubChem ID:24883031
Update Time:2025-06-07
3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid Chemical and Physical Properties
Names and Identifiers
-
- (3-Bromo-2-((3-methoxybenzyl)oxy)-5-methylphenyl)boronic acid
- 3-BROMO-5-METHYL-2-(3'-METHOXYBENZYLOXY)PHENYLBORONIC ACID
- 3-Bromo-5-methyl-2-(3-methoxybenzyloxy)phenylboronic acid
- Boronic acid,B-[3-bromo-2-[(3-methoxyphenyl)methoxy]-5-methylphenyl]-
- 3-Bromo-5-methyl-2-(3''-methoxybenzyloxy)phenylboronic Acid
- [3-bromo-2-[(3-methoxyphenyl)methoxy]-5-methylphenyl]boronic acid
- 3-BROMO-5-METHYL-2-(3'-METHOXYBENZYLOXY&
- 849062-23-3
- BS-22499
- AKOS015888498
- MFCD06411315
- (3-Bromo-2-((3-methoxybenzyl)oxy)-5-methylphenyl)boronicacid
- SCHEMBL9893668
- 3-BROMO-2-[(3-METHOXYPHENYL)METHOXY]-5-METHYLPHENYLBORONIC ACID
- C15H16BBrO4
- AB25214
- CS-0174353
- DTXSID90584546
- {3-Bromo-2-[(3-methoxyphenyl)methoxy]-5-methylphenyl}boronic acid
- 3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid
-
- MDL： MFCD06411315
- Inchi： 1S/C15H16BBrO4/c1-10-6-13(16(18)19)15(14(17)7-10)21-9-11-4-3-5-12(8-11)20-2/h3-8,18-19H,9H2,1-2H3
- InChI Key： KTEDZUFTBUUJLG-UHFFFAOYSA-N
- SMILES： BrC1=CC(C)=CC(B(O)O)=C1OCC1C=CC=C(C=1)OC
Computed Properties
- Exact Mass: 350.03300
- Monoisotopic Mass: 350.03250g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 2
- Hydrogen Bond Acceptor Count: 4
- Heavy Atom Count: 21
- Rotatable Bond Count: 5
- Complexity: 318
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Topological Polar Surface Area: 58.9?2
Experimental Properties
- Color/Form: No data available
- Density: Not available
- Melting Point: 113-118?°C (lit.)
- Boiling Point: Not available
- Flash Point: Not available
- Refractive Index: 1.607
- PSA: 58.92000
- LogP: 2.02490
- Vapor Pressure: Not available
3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid Security Information
- Signal Word：warning
- Hazard Statement： H413
-
Warning Statement：
P264Thoroughly clean after treatment
P280Wear protective gloves/Wear protective clothing/Wear protective goggles/Wear a protective mask
P305If it enters the eyes
P351Rinse carefully with water for a few minutes
P338Remove the contact lens(If any)And easy to operate,Continue flushing
P337If eye irritation persists
P313Obtain medical advice/care - Hazardous Material transportation number：NONH for all modes of transport
- WGK Germany：3
- Safety Instruction： H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
- Storage Condition：storage at -4℃ (1-2weeks), longer storage period at -20℃ (1-2years)
3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid Customs Data
- HS CODE：2931900090
- Customs Data：
China Customs Code:
2931900090Overview:
2931900090. Other organic-Inorganic compound. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:AB(Customs clearance form for Inbound Goods,Customs clearance form for outbound goods). MFN tariff:6.5%. general tariff:30.0%
Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| Matrix Scientific | 092732-250mg |
(3-Bromo-2-((3-methoxybenzyl)oxy)-5-methylphenyl)boronic acid, 95+% |
849062-23-3 | 95+% | 250mg |
$152.00 | 2023-09-10 | |
| Matrix Scientific | 092732-1g |
(3-Bromo-2-((3-methoxybenzyl)oxy)-5-methylphenyl)boronic acid, 95+% |
849062-23-3 | 95+% | 1g |
$336.00 | 2023-09-10 | |
| Fluorochem | 218427-250mg |
3-Bromo-2-((3-methoxybenzyl)oxy)-5-methylphenyl)boronic acid |
849062-23-3 | 95% | 250mg |
￡63.00 | 2022-03-01 | |
| Fluorochem | 218427-1g |
3-Bromo-2-((3-methoxybenzyl)oxy)-5-methylphenyl)boronic acid |
849062-23-3 | 95% | 1g |
￡150.00 | 2022-03-01 | |
| TRC | B694788-25mg |
3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid |
849062-23-3 | 25mg |
$ 64.00 | 2023-04-18 | ||
| TRC | B694788-50mg |
3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid |
849062-23-3 | 50mg |
$ 75.00 | 2023-04-18 | ||
| TRC | B694788-100mg |
3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid |
849062-23-3 | 100mg |
$ 87.00 | 2023-04-18 | ||
| TRC | B694788-250mg |
3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid |
849062-23-3 | 250mg |
$ 98.00 | 2023-04-18 | ||
| abcr | AB271692-250 mg |
3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid; 95% |
849062-23-3 | 250mg |
€127.00 | 2023-04-26 | ||
| Chemenu | CM137140-1g |
(3-Bromo-2-((3-methoxybenzyl)oxy)-5-methylphenyl)boronic acid |
849062-23-3 | 95% | 1g |
$181 | 2023-02-01 |
3-Bromo-5-methyl-2-(3'-methoxybenzyloxy)phenylboronic acid Related Literature
-
Jingquan Liu,Huiyun Liu,Zhongfan Jia,Volga Bulmus,Thomas P. Davis Chem. Commun., 2008, 6582-6584
-
James D. Kirkham,Patrick M. Delaney,George J. Ellames,Eleanor C. Row,Joseph P. A. Harrity Chem. Commun., 2010,46, 5154-5156
-
Chengbin Yang,Hing Lun Tsang,Pui Man Lau,Ken-Tye Yong,Ho Pui Ho,Siu Kai Kong Analyst, 2017,142, 3579-3587
-
5. An all-solid-state imprinted polymer-based potentiometric sensor for determination of bisphenol S?Rongning Liang,Tanji Yin,Ruiqing Yao,Wei Qin RSC Adv., 2016,6, 73308-73312
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