Cas no 84-11-7 (9,10-Phenanthrenequinone)

9,10-Phenanthrenequinone structure
9,10-Phenanthrenequinone structure
Product Name:9,10-Phenanthrenequinone
CAS No:84-11-7
MF:C14H8O2
MW:208.21212387085
MDL:MFCD00001163
CID:34308
PubChem ID:6763
Update Time:2024-10-26

9,10-Phenanthrenequinone Chemical and Physical Properties

Names and Identifiers

    • Phenanthrene-9,10-dione
    • 9,10-phenanthrenedione
    • 9,10-Phenanthraquinone
    • 9,10-Phenanthrenequinone
    • Phenanthrenechinone
    • Phenanthrenequinone
    • PHENANTHRENEQUINONE, SYNTHESIS GRADE
    • Phenanthraquinone
    • 9,10-Phenanthroquinone
    • SMR000150826
    • MLS000881132
    • MLS000571180
    • YYVYAPXYZVYDHN-UHFFFAOYSA-N
    • 42L7BZ8H74
    • 9,10-Phenanthrenedione Phenanthrenequinone
    • BP-13416
    • SB67051
    • STK793149
    • cid_6763
    • Z56943754
    • W-104124
    • EINECS 201-515-5
    • REGID_for_CID_6763
    • AF-936/31262009
    • BDBM22857
    • 9,10-Phenanthrenequinone, >=99%
    • Phenanthrene,10-dihydro-9,10-dioxo-
    • Phenanthrene, 9,10-dihydro-9,10-dioxo-
    • Phenanthrene chinone
    • Opera_ID_1159
    • DTXSID3058901
    • 84-11-7
    • D0Q2YJ
    • BRN 0608838
    • Phenanthroquinone
    • NSC 10446
    • WLN: L B666 HVVJ
    • EN300-17486
    • P0080
    • P1136
    • NCGC00246089-01
    • NSC10446
    • SR-01000512656
    • UNII-42L7BZ8H74
    • phenanthrenchinon
    • LS-102685
    • NSC7389
    • CHEMBL51931
    • CS-W015223
    • 9,10-dihydrophenanthrene-9,10-dione
    • phenanthrene-9,10-quinone
    • A840718
    • FT-0621602
    • 9,10-phenanthrenquinon
    • CX1139
    • SCHEMBL43050
    • AS-14257
    • 3-Pyrrolidin-2-yl-propionicacid
    • KSC-1-127
    • SR-01000512656-4
    • AKOS000120609
    • 9,10-phenanthrquinone
    • 9,10-Phenanthrenequinone, 95%
    • SR-01000512656-1
    • Phenanthrene-9,10 dione
    • HMS2231F24
    • 9-10 Phenanthrene quinone
    • 1,2-Dione-Based Compound, 14
    • NSC-7389
    • MFCD00001163
    • CHEBI:37454
    • 9,10-Phenanthrenequinone, Vetec(TM) reagent grade, 94%
    • 4-07-00-02565 (Beilstein Handbook Reference)
    • HSDB 4489
    • PHENANTHRENEQUINONE [MI]
    • Q-201551
    • CCRIS 7615
    • C03243
    • AI3-23739
    • NSC-10446
    • Q25103737
    • AMY37107
    • KUC103886N
    • Phenanthrenequinone (8CI)
    • NSC 7389
    • CS-006/03886049
    • DB-005403
    • NS00014591
    • MDL： MFCD00001163
    • Inchi： 1S/C14H8O2/c15-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14(13)16/h1-8H
    • InChI Key： YYVYAPXYZVYDHN-UHFFFAOYSA-N
    • SMILES： O=C1C2C(=CC=CC=2)C2C(=CC=CC=2)C1=O
    • BRN： 0608838

Computed Properties

  • Exact Mass: 208.05200
  • Monoisotopic Mass: 208.052
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 0
  • Hydrogen Bond Acceptor Count: 2
  • Heavy Atom Count: 16
  • Rotatable Bond Count: 0
  • Complexity: 289
  • Covalently-Bonded Unit Count: 1
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • XLogP3: 2.5
  • Topological Polar Surface Area: 34.1
  • Surface Charge: 0

Experimental Properties

  • Color/Form: Orange yellow needle like crystals.
  • Density: 1.405
  • Melting Point: 209-212?°C (lit.)
  • Boiling Point: 360 oC
  • Flash Point: Fahrenheit: 473 ° f
    Celsius: 245 ° c
  • Refractive Index: 1.5681 (estimate)
  • Solubility: 7.5mg/l
  • Water Partition Coefficient: Insoluble in water.
  • Stability/Shelf Life: Stable. Incompatible with strong oxidizing agents.
  • PSA: 34.14000
  • LogP: 2.73260
  • Merck: 7213
  • Solubility: Insoluble in water, slightly soluble in ethanol, benzene, ethyl acetate, soluble in ether and hot acetic acid
  • Vapor Pressure: 0.0±0.8 mmHg at 25°C

9,10-Phenanthrenequinone Security Information

  • Symbol: GHS07
  • Prompt：warning
  • Signal Word：Warning
  • Hazard Statement： H315,H319,H335
  • Warning Statement： P261,P305+P351+P338
  • Hazardous Material transportation number：UN3077
  • WGK Germany：3
  • Hazard Category Code： 36/37/38
  • Safety Instruction： S26-S36-S24/25-S22
  • RTECS：SF7875000
  • Hazardous Material Identification： Xi
  • HazardClass：9
  • PackingGroup：III
  • TSCA：Yes
  • Storage Condition：Store at room temperature
  • Safety Term：9
  • Packing Group：III
  • Risk Phrases：R36/37/38

9,10-Phenanthrenequinone Customs Data

  • HS CODE：29146990
  • Customs Data：

    China Customs Code:

    2914399090

    Overview:

    2914399090. Other aromatic ketones without other oxygen-containing groups. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:nothing. MFN tariff:5.5%. general tariff:30.0%

    Declaration elements:

    Product Name, component content, use to, Acetone declared packaging

    Summary:

    2914399090. other aromatic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

9,10-Phenanthrenequinone Pricemore >>

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9,10-Phenanthrenequinone Production Method

Production Method 1

Reaction Conditions
1.1 Reagents: 1,8-Diazabicyclo[5.4.0]undec-7-ene Solvents: tert-Butanol ;  24 h, 60 °C
1.2 Reagents: Oxygen
Reference
Thiazol-2-ylidene catalysis in intramolecular crossed aldehyde-ketone benzoin reactions
Enders, Dieter; Niemeier, Oliver, Synlett, 2004, (12), 2111-2114

Production Method 2

Reaction Conditions
1.1 Reagents: Sodium periodate Solvents: Dichloromethane ,  Water ;  10 min, rt
Reference
1-Methyl-1,4-cyclohexadiene as a Traceless Reducing Agent for the Synthesis of Catechols and Hydroquinones
Baschieri, Andrea ; Amorati, Riccardo ; Valgimigli, Luca ; Sambri, Letizia, Journal of Organic Chemistry, 2019, 84(21), 13655-13664

Production Method 3

Reaction Conditions
1.1 Reagents: Sodium bicarbonate ,  Potassium peroxymonosulfate sulfate (2KHSO5.KHSO4.K2SO4) Solvents: Acetone ,  Dichloromethane ,  Water
Reference
The formation of orthoquinones in the dimethyldioxirane oxidation of phenols
Crandall, Jack K.; Zucco, Martine; Kirsch, R. Scott; Coppert, David M., Tetrahedron Letters, 1991, 32(40), 5441-4

Production Method 4

Reaction Conditions
1.1 Reagents: Pyridine, 2,6-dichloro-, 1-oxide Catalysts: (OC-6-12)-Dichloro[5,10,15,20-tetrakis(2,6-dichlorophenyl)-21H,23H-porphinato(2-… Solvents: Dichloromethane ;  12 h, 40 °C
Reference
Dichlororuthenium(IV) complex of meso-tetrakis(2,6-dichlorophenyl)porphyrin: Active and robust catalyst for highly selective oxidation of arenes, unsaturated steroids, and electron-deficient alkenes by using 2,6-dichloropyridine N-oxide
Zhang, Jun-Long; Che, Chi-Ming, Chemistry - A European Journal, 2005, 11(13), 3899-3914

Production Method 5

Reaction Conditions
1.1 Reagents: Butyllithium ,  Hexamethylditin Solvents: Tetrahydrofuran ;  15 min, 0 °C
1.2 Solvents: Tetrahydrofuran ;  5 h, -78 °C
1.3 Reagents: Water ;  pH 7.0
Reference
Stanna-Brook Rearrangement of Carboxylic Acid Derivatives. Synthetic Utility and Mechanistic Studies
Paleo, M. Rita; Calaza, M. Isabel; Grana, Paula; Sardina, F. Javier, Organic Letters, 2004, 6(6), 1061-1063

Production Method 6

Reaction Conditions
1.1 Reagents: 1-Hexadecanaminium, N,N,N-trimethyl-, (T-4)-bromotrioxochromate(1-) (1:1) Solvents: Dichloromethane ;  72 min, reflux
Reference
Cetyltrimethylammonium bromochromate. A new and efficient oxidant for organic substrates
Ghammamy, Shahriar; Eimanieh, Hossein; Mohammady, Mohammad Kazem, Synthetic Communications, 2007, 37(4), 599-605

Production Method 7

Reaction Conditions
1.1 Reagents: 1-Butanaminium, N,N,N-tributyl-, (T-4)-fluorotrioxochromate(1-) Solvents: Dichloromethane ;  45 min, rt
Reference
Tetrabutylammonium fluorochromate(VI) (TBAFC). A mild and efficient reagent for oxidation of organic substrates
Ghammami, Shahriare; Sajadi, Seyed Abolfazl Seyed, Journal of the Serbian Chemical Society, 2005, 70(11), 1243-1248

Production Method 8

Reaction Conditions
1.1 Reagents: Methanaminium, N,N,N-trimethyl-, (T-4)-fluorotrioxochromate(1-) (1:1) Solvents: Dichloromethane ;  45 min, rt
Reference
Tetramethylammonium fluorochromate(VI): a new and efficient oxidant for organic substrates
Mahjoub, Ali Reza; Ghammami, Shahriare; Kassaee, Mohammad Zaman, Tetrahedron Letters, 2003, 44(24), 4555-4557

Production Method 9

Reaction Conditions
1.1 Reagents: Potassium carbonate ,  Sodium sulfate ,  Potassium peroxymonosulfate sulfate (2KHSO5.KHSO4.K2SO4) Solvents: Ethyl acetate ;  24 h, rt
1.2 Catalysts: Tetrabutylammonium hydrogen sulfate ,  Benzenesulfonic acid, 2-iodo-5-methyl-, sodium salt (1:1) Solvents: Ethyl acetate ;  3 h, 40 °C
Reference
IBS-catalyzed regioselective oxidation of phenols to 1,2-quinones with Oxone
Uyanik, Muhammet; Mutsuga, Tatsuya; Ishihara, Kazuaki, Molecules, 2012, 17, 8604-8616

Production Method 10

Reaction Conditions
1.1 Reagents: Chromate(1-), chlorotrioxo-, (T-4)-, hydrogen, compd. with N,N-dipropyl-1-propan… Solvents: Dichloromethane ;  rt; 350 min, rt
Reference
The two new tripropylammonium halochromates, (C3H7)3NH[CrO3X], (X = F, Cl), reagents for oxidation of alcohols on alumina
Ghammamy, Shahriar; Sharifnezhad, Zahra; Aghbolagh, Zahra Shokri; Sahebalzamani, Hajar, Advances in Applied Science Research, 2010, 1(2), 119-123

Production Method 11

Reaction Conditions
1.1 Reagents: Chromate(1-), chlorotrioxo-, (T-4)-, hydrogen, compd. with N,N-dimethylmethanami… Solvents: Dichloromethane ;  rt; 8 h, rt
Reference
Heterogeneous oxidation of organic substrates by using two trimethylammonium halochromates on alumina, (CH3)3NH[CrO3X], (X=F, Cl)
Ghammamy, Shahriare; Moghimi, Ali; Nezhad, Zahra Sharif; Aghbolagh, Zahra Shokri; Behbahani, Golam Rezaei, Chemica Sinica, 2010, 1(1), 106-110

Production Method 12

Reaction Conditions
1.1 Reagents: Acetic acid ,  Ceric sulfate Catalysts: Iridium trichloride ;  3 h, 100 °C
Reference
Liquid-Phase and Solventless Oxidation of Cyclohexane, Benzene, and Other Hydrocarbons by Cerium(IV) Catalyzed by Iridium(III) in Acidic Medium
Tandon, Praveen K.; Srivastava, Manish; Singh, Santosh B.; Srivastava, Nidhi, Synthetic Communications, 2008, 38(18), 3183-3192

9,10-Phenanthrenequinone Raw materials

9,10-Phenanthrenequinone Preparation Products

9,10-Phenanthrenequinone Suppliers

Amadis Chemical Company Limited
Gold Member
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(CAS:84-11-7)9,10-Phenanthrenequinone
Order Number:A840718
Stock Status:in Stock
Quantity:500g
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 06:50
Price ($):275.0
Suzhou Senfeida Chemical Co., Ltd
Gold Member
Audited Supplier Audited Supplier
(CAS:84-11-7)Phenanthrenequinone
Order Number:sfd14120
Stock Status:in Stock
Quantity:200kg
Purity:99.9%
Pricing Information Last Updated:Friday, 19 July 2024 14:36
Price ($):discuss personally
Tiancheng Chemical (Jiangsu) Co., Ltd
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(CAS:84-11-7)9,10-Phenanthrenequinone, ≥ 99.0%
Order Number:LE15164;LE1710069
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 12:12
Price ($):discuss personally

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Amadis Chemical Company Limited
(CAS:84-11-7)9,10-Phenanthrenequinone
A840718
Purity:99%
Quantity:500g
Price ($):275.0
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Suzhou Senfeida Chemical Co., Ltd
(CAS:84-11-7)Phenanthrenequinone
sfd14120
Purity:99.9%
Quantity:200kg
Price ($):Inquiry
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