Cas no 83282-91-1 (4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol)

4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol structure
83282-91-1 structure
Product Name:4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol
CAS No:83282-91-1
MF:C9H8F4O2
MW:224.152236938477
MDL:MFCD08688060
CID:60555
PubChem ID:11172116
Update Time:2024-10-27

4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol Chemical and Physical Properties

Names and Identifiers

    • (2,3,5,6-Tetrafluoro-4-(methoxymethyl)phenyl)methanol
    • 4-Methoxymethyl-2,3,5,6-tetrafluorobenzenemethanol
    • 4-Methoxy methyl -2,3,5,6-tetrafluorobenzyl alcoho
    • 4-Methoxymethyl-2,3,5,6-Tetrafluorobenzyl Alcohol
    • 2,3,5,6-Tetrafluoro-4-methoxybenzyl alcohol
    • 4-METHOXYMETHYL-2,3,5,6-TETRAFLUOROBENZYL
    • 2,3,5,6-Tetrafluoro-4-(methoxymethyl)benzylalcohol
    • 2,3,5,6-Tetrafluoro-4-(methoxymethyl)benzyl alcohol
    • 2,3,5,6-Tetrafluoro-4-(methoxymethyl)benzenemethanol (ACI)
    • [2,3,5,6-Tetrafluoro-4-(methoxymethyl)phenyl]methanol
    • AM20041227
    • 4-Methoxymethyl-2,3,5,6-tetrafluorobenzylalcohol
    • 83282-91-1
    • Benzenemethanol, 2,3,5,6-tetrafluoro-4-(methoxymethyl)-
    • DTXSID90457625
    • EN300-6764203
    • 4-Methoxymethyl -2, 3, 5, 6-tetrafluorobenzyl alcohol
    • AC-8278
    • 4-(Methoxymethyl)-2,3,5,6-tetrafluorobenzyl alcohol
    • SY284773
    • Benzenemethanol, 2,3,5,6-tetrafluoro-4-(methoxymethyl)
    • 2,3,5,6-tetrafluoro-4-methoxymethylbenzylalcohol
    • CS-0150199
    • MFCD08688060
    • YFHZSPDQKWFAPH-UHFFFAOYSA-N
    • AS-11390
    • FT-0655937
    • 2,3,5,6-Tetrafluoro-4-(methoxymethyl)-benzenemethanol; 2,3,5,6-Tetrafluoro-4-(methoxymethyl)benzyl Alcohol
    • D82272
    • 4-(methoxymethyl)-2,3,5,6-tetrafluorobenzylalcohol
    • 4-methoxymethy-2,3,5,6-tetrafluorobenzyl alcohol
    • 4-Methoxymethyl -2,3,5,6-tetrafluorobenzyl alcohol
    • AKOS015852458
    • 4-methoxymethyl-2,3,5, 6-tetrafluorobenzyl alcohol
    • SCHEMBL359266
    • 4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol
    • MDL： MFCD08688060
    • Inchi： 1S/C9H8F4O2/c1-15-3-5-8(12)6(10)4(2-14)7(11)9(5)13/h14H,2-3H2,1H3
    • InChI Key： YFHZSPDQKWFAPH-UHFFFAOYSA-N
    • SMILES： FC1C(CO)=C(F)C(F)=C(COC)C=1F

Computed Properties

  • Exact Mass: 224.04600
  • Monoisotopic Mass: 224.04604214g/mol
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 1
  • Hydrogen Bond Acceptor Count: 2
  • Heavy Atom Count: 15
  • Rotatable Bond Count: 3
  • Complexity: 189
  • Covalently-Bonded Unit Count: 1
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Surface Charge: 0
  • Tautomer Count: nothing
  • XLogP3: 1.1
  • Topological Polar Surface Area: 29.5?2

Experimental Properties

  • Density: 1.407
  • Melting Point: 51-54°C
  • Boiling Point: 214 oC
  • Flash Point: 107 oC
  • Refractive Index: 1.464
  • PSA: 29.46000
  • LogP: 1.88170
  • Vapor Pressure: 0.0±0.5 mmHg at 25°C

4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol Security Information

4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol Customs Data

  • HS CODE：2942000000
  • Customs Data：

    China Customs Code:

    2909499000

    Overview:

    2909499000 Other ether alcohols and their halogenation\sulfonation\Nitrosative or nitrosative derivatives. VAT:17.0% Tax refund rate:9.0% Regulatory conditions:nothing MFN tariff:5.5% general tariff:30.0%

    Declaration elements:

    Product Name, component content, use to

    Summary:

    2909499000. ether-alcohols and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%

4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol Pricemore >>

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4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol Production Method

Production Method 1

Reaction Conditions
1.1 Reagents: Zinc chloride ,  Sodium borohydride Solvents: Diglyme ;  24 h, rt
1.2 Solvents: Diglyme ;  5 h, reflux
1.3 Reagents: Sulfuric acid Solvents: Water
Reference
A new synthetic route to polyfluorobenzyl alcohol
Zhang, Deyan; et al, Journal of Fluorine Chemistry, 2009, 130(10), 938-941

Production Method 2

Reaction Conditions
1.1 Reagents: Sodium borohydride Catalysts: Tetrabutylammonium chloride ,  Aluminum chloride Solvents: Tetrahydrofuran ;  rt; rt → reflux; 8 h, reflux; reflux → rt
1.2 Reagents: Hydrochloric acid Solvents: Water
2.1 Reagents: Sodium hydroxide Solvents: Toluene ,  Water ;  40 - 50 °C; 2 h, 40 - 50 °C
Reference
Research on synthesis of 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl alcohol
Yuan, Qiliang; et al, Huagong Shengchan Yu Jishu, 2013, 20(6), 11-14

Production Method 3

Reaction Conditions
1.1 Reagents: Sodium hydroxide Solvents: Toluene ,  Water ;  pH 8 - 9, 20 - 25 °C; 25 °C → 35 °C
1.2 30 - 35 °C; 5 h, 30 - 35 °C
Reference
Synthesis of tetramethylfluthrin
He, Shu-ze, Xiandai Nongyao, 2014, 13(6), 22-24

Production Method 4

Reaction Conditions
1.1 Reagents: Sodium hydroxide Solvents: Toluene ,  Water ;  40 - 50 °C; 2 h, 40 - 50 °C
Reference
Research on synthesis of 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl alcohol
Yuan, Qiliang; et al, Huagong Shengchan Yu Jishu, 2013, 20(6), 11-14

Production Method 5

Reaction Conditions
Reference
Metabolism of the Pyrethroid Insecticide Momfluorothrin in Lettuce (Lactuca sativa L.)
Matsushima, Keita ; et al, Journal of Agricultural and Food Chemistry, 2021, 69(22), 6156-6165

Production Method 6

Reaction Conditions
1.1 Reagents: Potassium fluoride Solvents: Dimethylformamide ;  6 - 10 h, 150 - 160 °C
1.2 Reagents: Sulfuric acid Solvents: Water ;  4 - 6 h, 60 - 80 °C
1.3 Reagents: Thionyl chloride Solvents: Toluene ;  rt → reflux; 6 h, reflux; reflux → rt
1.4 Reagents: Sodium borohydride Solvents: Tetrahydrofuran ;  6 h, heated
1.5 Reagents: Hydrochloric acid Solvents: Water ;  acidified
1.6 Reagents: Hydrogen bromide Solvents: Toluene ;  8 - 20 h, 75 - 85 °C; 85 °C → rt
1.7 Reagents: Sodium methoxide Solvents: Toluene ;  10 - 20 h, 50 - 60 °C; 60 °C → rt
1.8 Reagents: Water
Reference
Synthesis of 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylic acid [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl ester
Chen, Jianhai; et al, Nongyao, 2005, 44(9), 405-406

Production Method 7

Reaction Conditions
1.1 Reagents: Butyllithium Solvents: Diethyl ether ;  20 min, -78 °C; 60 min, -78 °C
1.2 1 h, -60 °C; -60 °C → rt; rt
1.3 40 min, rt
1.4 Reagents: Hydrochloric acid Solvents: Water
2.1 Reagents: Zinc chloride ,  Sodium borohydride Solvents: Diglyme ;  24 h, rt
2.2 Solvents: Diglyme ;  5 h, reflux
2.3 Reagents: Sulfuric acid Solvents: Water
Reference
A new synthetic route to polyfluorobenzyl alcohol
Zhang, Deyan; et al, Journal of Fluorine Chemistry, 2009, 130(10), 938-941

Production Method 8

Reaction Conditions
Reference
Metabolism of the Pyrethroid Insecticide Momfluorothrin in Lettuce (Lactuca sativa L.)
Matsushima, Keita ; et al, Journal of Agricultural and Food Chemistry, 2021, 69(22), 6156-6165

4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol Raw materials

4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol Preparation Products

4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol Suppliers

Suzhou Senfeida Chemical Co., Ltd
Gold Member
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(CAS:83282-91-1)4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl alcohol
Order Number:sfd6311;1669024
Stock Status:in Stock
Quantity:200kg/Company Customization
Purity:99.9%/98%
Pricing Information Last Updated:Friday, 19 July 2024 14:34
Price ($):discuss personally
Amadis Chemical Company Limited
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(CAS:83282-91-1)4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol
Order Number:A840554
Stock Status:in Stock
Quantity:1kg/500g
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 06:50
Price ($):423.0/275.0
Tiancheng Chemical (Jiangsu) Co., Ltd
Gold Member
Audited Supplier Audited Supplier
(CAS:83282-91-1)4-Methoxymethyl-2,3,5,6-tetrafluorobenzenemethanol
Order Number:LE9529;LE1669024
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 12:01
Price ($):discuss personally

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Suzhou Senfeida Chemical Co., Ltd
(CAS:83282-91-1)4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl alcohol
sfd6311;1669024
Purity:99.9%/98%
Quantity:200kg/Company Customization
Price ($):Inquiry/Inquiry
Email
Amadis Chemical Company Limited
(CAS:83282-91-1)4-Methoxymethyl-2,3,5,6-tetrafluorobenzyl Alcohol
A840554
Purity:99%/99%
Quantity:1kg/500g
Price ($):423.0/275.0
Email