Production Method 1

66932-75-0

7311-34-4

807372-38-9

Reaction Conditions

1.1 Reagents: Potassium carbonate ;  60 min, rt

Reference

First mechanosynthesis of piperlotines A, C, and derivatives through solvent-free Horner-Wadsworth-Emmons reaction

Ramirez-Marroquin, Oscar Abelardo; et al, Synthetic Communications, 2019, 49(2), 244-255

Production Method 2

171290-52-1

807372-38-9

Reaction Conditions

1.1 Reagents: Triethylamine Catalysts: Iron, di-μ-carbonyldecacarbonyltri-, triangulo ,  [N(E),N′(E)]-N,N′-(1,2-Dimethyl-1,2-ethanediylidene)bis[2,6-bis(1-methylethyl)be… Solvents: Tetrahydrofuran ;  16 h, 10 bar, 120 °C

Reference

A General and Selective Iron-Catalyzed Aminocarbonylation of Alkynes: Synthesis of Acryl- and Cinnamides

Driller, Katrin Marie; et al, Angewandte Chemie, 2011, 50(2), 537-541

Production Method 3

90892-09-4

807372-38-9

Reaction Conditions

1.1 4.5 h, 60 °C
2.1 Reagents: Potassium carbonate ;  60 min, rt

Reference

First mechanosynthesis of piperlotines A, C, and derivatives through solvent-free Horner-Wadsworth-Emmons reaction

Ramirez-Marroquin, Oscar Abelardo; et al, Synthetic Communications, 2019, 49(2), 244-255

Production Method 4

598-21-0

807372-38-9

Reaction Conditions

1.1 Solvents: Dichloromethane ;  0 - 25 °C; overnight, 25 °C
1.2 Solvents: Water
2.1 4.5 h, 60 °C
3.1 Reagents: Potassium carbonate ;  60 min, rt

Reference

First mechanosynthesis of piperlotines A, C, and derivatives through solvent-free Horner-Wadsworth-Emmons reaction

Ramirez-Marroquin, Oscar Abelardo; et al, Synthetic Communications, 2019, 49(2), 244-255

4'-Demethoxypiperlotine C Raw materials

• 2-bromo-1-(pyrrolidin-1-yl)ethan-1-one
• Phosphonic acid, [2-oxo-2-(1-pyrrolidinyl)ethyl]-, diethyl ester
• 2-BROMOACETYL BROMIDE
• 3,5-Dimethoxyphenylacetylene
• 3,5-Dimethoxybenzaldehyde

4'-Demethoxypiperlotine C Preparation Products

• 4'-Demethoxypiperlotine C (807372-38-9)

• 1. Establishment and implications of a characterization method for magnetic nanoparticle using cell tracking velocimetry and magnetic susceptibility modified solutions
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• 2. Exciton manipulation in rippled transition metal dichalcogenides?
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• 3. Fe(iii)-mediated isomerization of α,α-diarylallylic alcohols to ketones via radical 1,2-aryl migration?
  Ziyang Deng,Changwei Chen,Sunliang Cui RSC Adv., 2016,6, 93753-93755
• 4. Excellent peroxidase mimicking property of CuO/Pt nanocomposites and their application as an ascorbic acid sensor?
  Xinhuan Wang,Shuangfei Cai,Cui Qi Analyst, 2017,142, 2500-2506
• 5. Exciplex emission from the mixed dimer of naphthalene and 2-cyanonaphthalene in a supersonic jet
  Aloke Das,K. K. Mahato,Chayan K. Nandi,Tapas Chakraborty,Shridhar R. Gadre,Nikhil A. Gokhale Phys. Chem. Chem. Phys., 2002,4, 2162-2168

• Solvents and Organic Chemicals Organic Compounds Phenylpropanoids and polyketides Cinnamic acids and derivatives Cinnamic acids and derivatives
• Solvents and Organic Chemicals Organic Compounds Phenylpropanoids and polyketides Cinnamic acids and derivatives

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• 2098070-20-1(2-(3-(Pyridin-3-yl)-1H-pyrazol-1-yl)acetimidamide)
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