Production Method 1

78831-87-5

Reaction Conditions

1.1 Reagents: Hydrogen bromide Solvents: Acetic acid ;  2 h, 50 °C

Reference

Synthesis of 2,2-dimethyl-3-(3-methylphenyl)propanal and its derivatives

Zhang, Jianshui; Huang, Rui; Yan, Qian; Pan, Xiahua; Liu, Feng; et al, Asian Journal of Chemistry, 2013, 25(3), 1290-1292

Production Method 2

16308-92-2

78831-87-5

Reaction Conditions

1.1 Reagents: Pyridinium tribromide

Reference

Synthesis and antirhinovirus activity of 6-(dimethylamino)-2-(trifluoromethyl)-9-(substituted benzyl)-9H-purines

Kelley, James L.; Linn, James A.; Selway, J. W. T., Journal of Medicinal Chemistry, 1989, 32(8), 1757-63

Production Method 3

16308-92-2

78831-87-5

Reaction Conditions

1.1 Reagents: Phosphorus tribromide Solvents: Dichloromethane ;  rt → 0 °C; 0 °C; 2 h, rt
1.2 Reagents: Water

Reference

Paracyclophanes. Part 58. On the use of the stilbene-phenanthrene photocyclization in [2.2]paracyclophane chemistry

Hopf, H.; Hucker, J.; Ernst, L., Polish Journal of Chemistry, 2007, 81(5-6), 947-969

Production Method 4

16308-92-2

78831-87-5

Reaction Conditions

1.1 Reagents: Acetyl bromide

Reference

Mechanism of solvolyses of substituted benzyl bromides in 80% ethanol

Matic, Mirela; Denegri, Bernard ; Zupan, Tina, Croatica Chemica Acta, 2021, 94(3), 185-189

Production Method 5

78831-87-5

94416-66-7

50837-53-1

Reaction Conditions

1.1 Reagents: Benzoic acid ,  tert-Butyl hydroperoxide ,  Copper bromide (CuBr) Solvents: tert-Butanol ,  1,2,4-Trimethylbenzene ;  5 h, 80 °C
1.2 Reagents: Sodium thiosulfate Solvents: Dichloromethane

Reference

Effective synthesis of benzyl halides triggered by in situ prepared hypervalent halides

Ling, Xue-Ge; Xiong, Yan; Zhang, Shu-Ting; Huang, Ruo-Feng; Zhang, Xiao-Hui, Chinese Chemical Letters, 2013, 24(1), 45-48

2,4-Dimethylbenzyl bromide Raw materials

• (2,4-Dimethylphenyl)methanol

2,4-Dimethylbenzyl bromide Preparation Products

• 4-(bromomethyl)-1,2-dimethylbenzene (94416-66-7)
• 2-(bromomethyl)-1,4-dimethylbenzene (50837-53-1)
• 2,4-Dimethylbenzyl bromide (78831-87-5)

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• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Benzyl halides Benzyl bromides

• 83902-02-7(2-(Bromomethyl)-1,3-dimethylbenzene)
• 3095-73-6(Hexakis(bromomethyl)benzene)
• 35168-62-8(1,4-Bis(bromomethyl)-2,5-dimethylbenzene)
• 38622-14-9(Benzene, bis(bromomethyl)-)
• 28777-60-8(Benzene,(bromomethyl)methyl-)
• 104155-11-5(Benzene,(bromomethyl)dimethyl- (9CI))
• 15442-91-8(1,2,4,5-Tetrakis(bromomethyl)benzene)
• 21988-87-4(2,4,6-Tris(bromomethyl)mesitylene)
• 91-13-4(1,2-Bis(bromomethyl)benzene)
• 35168-64-0(3,6-Bis(bromomethyl)durene)