Production Method 1

53520-46-0

4737-41-1

53521-23-6

918-84-3

62016-93-7

Reaction Conditions

1.1 Reagents: Carbon tetrachloride ,  N-(1,1-Dimethylethyl)-N-[(1-phenylethenyl)oxy]-3,5-bis(trifluoromethyl)benzamide Solvents: (Trifluoromethyl)benzene ;  16 h, rt → 60 °C

Reference

Diversification of aliphatic C-H bonds in small molecules and polyolefins through radical chain transfer

Fazekas, Timothy J. ; Alty, Jill W. ; Neidhart, Eliza K. ; Miller, Austin S. ; Leibfarth, Frank A. ; et al, Science (Washington, 2022, 375(6580), 545-550

Pentane, 2-chloro-3-methyl-, (R*,S*)- (9CI) Preparation Products

• 3-(chloromethyl)pentane (4737-41-1)
• Pentane, 2-chloro-3-methyl-, (R*,R*)- (9CI) (53521-23-6)
• Pentane,3-chloro-3-methyl- (918-84-3)
• Pentane, 2-chloro-3-methyl-, (R*,S*)- (9CI) (53520-46-0)
• Pentane, 1-chloro-3-methyl- (62016-93-7)

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  P. K. Wawrzyniak,M. T. P. Beerepoot,H. J. M. de Groot,F. Buda Phys. Chem. Chem. Phys., 2011,13, 10270-10279

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