- ''Bulky-Yet-Flexible'' α-Diimine Palladium-Catalyzed Reductive Heck Cross-Coupling: Highly Anti-Markovnikov-Selective Hydroarylation of Alkene in AirBy Yang, Xu-Wen et al, Journal of Organic Chemistry, 2020, 85(18), 11750-11765
Cas no 2227355-48-6 (Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]-)
2227355-48-6 structure
Product Name:Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]-
CAS No:2227355-48-6
MF:C19H24
MW:252.393865585327
CID:5597190
Update Time:2023-08-23
Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]- Chemical and Physical Properties
Names and Identifiers
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- Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]-
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- Inchi: 1S/C19H24/c1-15-5-7-16(8-6-15)9-10-17-11-13-18(14-12-17)19(2,3)4/h5-8,11-14H,9-10H2,1-4H3
- InChI Key: SBTUIDZIGRCBHE-UHFFFAOYSA-N
- SMILES: C1(CCC2C=CC(C)=CC=2)=CC=C(C(C)(C)C)C=C1
Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]- Production Method
Production Method 1
Reaction Conditions
1.1R:C:2485728-46-7, S:BuOH, 4 h, 80°C
Reference
Production Method 2
Reaction Conditions
1.1R:KOH, C:2106811-81-6, S:Me2CHOH, 12 h, 75°C; 75°C → rt
1.2R:mCPBA, S:CH2Cl2, 0-10°C
1.2R:mCPBA, S:CH2Cl2, 0-10°C
Reference
- Pd-Catalyzed reductive Heck reaction of olefins with aryl bromides for Csp2-Csp3 bond formationBy Jin, Liqun et al, Chemical Communications (Cambridge, 2018, 54(45), 5752-5755
Production Method 3
Reaction Conditions
1.1R:TMBAC, S:MeCN, 3 h, rt
Reference
- Electroreduction Enables Regioselective 1,2-Diarylation of Alkenes with Two ElectrophilesBy Yu, Weijie et al, Angewandte Chemie, 2023, 62(17), e202219166
Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]- Raw materials
Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]- Preparation Products
Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]- Related Literature
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Huabin Zhang,Shaowu Du CrystEngComm, 2014,16, 4059-4068
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Jianyao Huang,Dong Gao,Zhihui Chen,Weifeng Zhang Polym. Chem., 2021,12, 2471-2480
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José M. Rivera,Mariana Martín-Hidalgo,Jean C. Rivera-Ríos Org. Biomol. Chem., 2012,10, 7562-7565
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Hyejin Moon,Aaron R. Wheeler,Robin L. Garrell,Chang-Jin “CJ” Kim Lab Chip, 2006,6, 1213-1219
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Huiying Xu,Lu Zheng,Yu Zhou,Bang-Ce Ye Analyst, 2021,146, 5542-5549
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