Cas no 2227355-48-6 (Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]-)

Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]- structure
2227355-48-6 structure
Product Name:Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]-
CAS No:2227355-48-6
MF:C19H24
MW:252.393865585327
CID:5597190
Update Time:2023-08-23

Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]- Chemical and Physical Properties

Names and Identifiers

    • Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]-
    • Inchi: 1S/C19H24/c1-15-5-7-16(8-6-15)9-10-17-11-13-18(14-12-17)19(2,3)4/h5-8,11-14H,9-10H2,1-4H3
    • InChI Key: SBTUIDZIGRCBHE-UHFFFAOYSA-N
    • SMILES: C1(CCC2C=CC(C)=CC=2)=CC=C(C(C)(C)C)C=C1

Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]- Production Method

Production Method 1

Reaction Conditions
1.1R:C:2485728-46-7, S:BuOH, 4 h, 80°C
Reference
''Bulky-Yet-Flexible'' α-Diimine Palladium-Catalyzed Reductive Heck Cross-Coupling: Highly Anti-Markovnikov-Selective Hydroarylation of Alkene in Air
By Yang, Xu-Wen et al, Journal of Organic Chemistry, 2020, 85(18), 11750-11765

Production Method 2

Reaction Conditions
1.1R:KOH, C:2106811-81-6, S:Me2CHOH, 12 h, 75°C; 75°C → rt
1.2R:mCPBA, S:CH2Cl2, 0-10°C
Reference
Pd-Catalyzed reductive Heck reaction of olefins with aryl bromides for Csp2-Csp3 bond formation
By Jin, Liqun et al, Chemical Communications (Cambridge, 2018, 54(45), 5752-5755

Production Method 3

Reaction Conditions
1.1R:TMBAC, S:MeCN, 3 h, rt
Reference
Electroreduction Enables Regioselective 1,2-Diarylation of Alkenes with Two Electrophiles
By Yu, Weijie et al, Angewandte Chemie, 2023, 62(17), e202219166

Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]- Raw materials

Benzene, 1-(1,1-dimethylethyl)-4-[2-(4-methylphenyl)ethyl]- Preparation Products

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