Cas no 137203-34-0 (1,4-Diazabicyclo2.2.2Octane Bis(Trimethylaluminum) Complex)

The 1,4-Diazabicyclo[2.2.2]octane Bis(Trimethylaluminum) Complex is a highly reactive organometallic compound, primarily utilized as a catalyst or reagent in organic synthesis and polymerization processes. Its key advantages include strong Lewis acidity, derived from the trimethylaluminum (TMA) component, and the stabilizing effect of the 1,4-diazabicyclo[2.2.2]octane (DABCO) ligand, which enhances its handling and reactivity control. This complex is particularly effective in catalyzing carbon-carbon bond formation and ring-opening polymerizations, offering precise selectivity under mild conditions. Its stability in solution and compatibility with various substrates make it a valuable tool in advanced synthetic chemistry applications.
1,4-Diazabicyclo2.2.2Octane Bis(Trimethylaluminum) Complex structure
137203-34-0 structure
Product Name:1,4-Diazabicyclo2.2.2Octane Bis(Trimethylaluminum) Complex
CAS No:137203-34-0
MF:C12H30Al2N2
MW:256.343080997467
MDL:MFCD09265160
CID:1243923
PubChem ID:24885678
Update Time:2025-06-09

1,4-Diazabicyclo2.2.2Octane Bis(Trimethylaluminum) Complex Chemical and Physical Properties

Names and Identifiers

    • 1,4-diazabicyclo[2.2.2]octane,trimethylalumane
    • 1,4-DIAZABICYCLO[2.2.2]OCTANE BIS(TRIMETHYLALUMINUM) COMPLEX
    • Bis(trimethylaluminium)-1,4-diazabicyclo-[2.2.2]octane adduct (DABAL-Me3)
    • BIS(TRIMETHYLALUMINUM)-1,4-DIAABICYCLO[2.2.2]OCTANE ADDUCT
    • Bis(trimethylaluminum)-DABCO(R) adduct, DABAL-Me3, DABAL-trimethylaluminum, Triethylenediaminine bis(trimethylaluminum)
    • Bis(triMethylaluMinuM)-1,4-diazabicyclo[2.2.2]octane Adduct
    • DABAL-Me3
    • DABAL-trimethylaluminum
    • SCHEMBL173954
    • J-006979
    • 137203-34-0
    • MFCD09265160
    • DTXSID20586917
    • AKOS025294430
    • 1,4-Diazabicyclo[2.2.2]octane--trimethylalumane (1/2)
    • 1,4-diazabicyclo[2.2.2]octane;trimethylalumane
    • 1,4-Diazabicyclo2.2.2Octane Bis(Trimethylaluminum) Complex
    • MDL： MFCD09265160
    • Inchi： 1S/C6H12N2.6CH3.2Al/c1-2-8-5-3-7(1)4-6-8;;;;;;;;/h1-6H2;6*1H3;;
    • InChI Key： WSTAITCRSVOCTK-UHFFFAOYSA-N
    • SMILES： [Al](C)(C)C.[Al](C)(C)C.N12CCN(CC1)CC2

Computed Properties

  • Exact Mass: 268.29800
  • Monoisotopic Mass: 256.203976g/mol
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 0
  • Hydrogen Bond Acceptor Count: 2
  • Heavy Atom Count: 16
  • Rotatable Bond Count: 0
  • Complexity: 69.5
  • Covalently-Bonded Unit Count: 3
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Topological Polar Surface Area: 6.5?2

Experimental Properties

  • Melting Point: >250?°C
  • PSA: 6.48000
  • LogP: 3.98500

1,4-Diazabicyclo2.2.2Octane Bis(Trimethylaluminum) Complex Security Information

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Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct; .
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Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct; .
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abcr
AB331639-5 g
Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct; .
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1,4-Diazabicyclo2.2.2Octane Bis(Trimethylaluminum) Complex Production Method

1,4-Diazabicyclo2.2.2Octane Bis(Trimethylaluminum) Complex Related Literature

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