Production Method 1

1342864-93-0

1342865-02-4

824-42-0

1259480-34-6

Reaction Conditions

1.1 Solvents: N-Methyl-2-pyrrolidone ;  1 min, rt → 230 °C; 2 min, 230 °C

Reference

Effective Synthesis of ortho-Substituted Trithiophenol Amines by Miyazaki-Newman-Kwart Rearrangement

Gjoka, Blerina; et al, European Journal of Organic Chemistry, 2011, 2011(28), 5636-5640

Production Method 2

824-42-0

16420-13-6

1342865-02-4

824-42-0

1259480-34-6

Reaction Conditions

1.1 Reagents: Potassium carbonate Solvents: Acetonitrile ;  10 min, rt
1.2 24 h, 80 °C
2.1 Solvents: N-Methyl-2-pyrrolidone ;  1 min, rt → 230 °C; 2 min, 230 °C

Reference

Effective Synthesis of ortho-Substituted Trithiophenol Amines by Miyazaki-Newman-Kwart Rearrangement

Gjoka, Blerina; et al, European Journal of Organic Chemistry, 2011, 2011(28), 5636-5640

Carbamothioic acid, N,N-dimethyl-, S-(2-formyl-6-methylphenyl) ester Raw materials

• Carbamothioic acid, N,N-dimethyl-, O-(2-formyl-6-methylphenyl) ester
• 2-Hydroxy-3-methylbenzaldehyde
• Dimethylthyocarbamoyl cloride

Carbamothioic acid, N,N-dimethyl-, S-(2-formyl-6-methylphenyl) ester Preparation Products

• Carbamothioic acid, N,N-dimethyl-, S-(2-formyl-6-methylphenyl) ester (1342865-02-4)
• 2-Hydroxy-3-methylbenzaldehyde (824-42-0)
• Benzaldehyde, 2-mercapto-3-methyl- (1259480-34-6)

• 1. Aluminium alkyl and aryloxide complexes of pyrazine and bipyridines: synthesis and structure?
  Doug Ogrin,Laura H. van Poppel,Simon G. Bott,Andrew R. Barron Dalton Trans., 2004, 3689-3694
• 2. An atom efficient route to N-aryl and N-alkyl pyrrolines by transition metal catalysis?
  Supaporn Sawadjoon,Joseph S. M. Samec Org. Biomol. Chem., 2011,9, 2548-2554
• 3. An astrophysically-relevant mechanism for amino acid enantiomer enrichment
  Stephen P. Fletcher,Richard B. C. Jagt,Ben L. Feringa Chem. Commun., 2007, 2578-2580
• 4. Acentric and chiral heterometallic inorganic–organic hybrid frameworks mediated by alkali or alkaline earth ions: synthesis and NLO properties
  Huabin Zhang,Shaowu Du CrystEngComm, 2014,16, 4059-4068
• 5. An amorphous carbon nitride/NiO/CoN-based composite: a highly efficient nonprecious electrode for supercapacitors and the oxygen evolution reaction?
  Huifang Yang,Haoran Guo,Peidong Fan,Xinpan Li,Wenlu Ren,Rui Song Nanoscale, 2020,12, 7024-7034

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