Production Method 1

1342864-93-0

1259480-34-6

1342865-02-4

824-42-0

Reaction Conditions

1.1 Solvents: N-Methyl-2-pyrrolidone ;  1 min, rt → 230 °C; 2 min, 230 °C

Reference

Effective Synthesis of ortho-Substituted Trithiophenol Amines by Miyazaki-Newman-Kwart Rearrangement

Gjoka, Blerina; et al, European Journal of Organic Chemistry, 2011, 2011(28), 5636-5640

Production Method 2

824-42-0

16420-13-6

1259480-34-6

1342865-02-4

824-42-0

Reaction Conditions

1.1 Reagents: Potassium carbonate Solvents: Acetonitrile ;  10 min, rt
1.2 24 h, 80 °C
2.1 Solvents: N-Methyl-2-pyrrolidone ;  1 min, rt → 230 °C; 2 min, 230 °C

Reference

Effective Synthesis of ortho-Substituted Trithiophenol Amines by Miyazaki-Newman-Kwart Rearrangement

Gjoka, Blerina; et al, European Journal of Organic Chemistry, 2011, 2011(28), 5636-5640

Benzaldehyde, 2-mercapto-3-methyl- Raw materials

• Carbamothioic acid, N,N-dimethyl-, O-(2-formyl-6-methylphenyl) ester
• 2-Hydroxy-3-methylbenzaldehyde
• Dimethylthyocarbamoyl cloride

Benzaldehyde, 2-mercapto-3-methyl- Preparation Products

• Carbamothioic acid, N,N-dimethyl-, S-(2-formyl-6-methylphenyl) ester (1342865-02-4)
• 2-Hydroxy-3-methylbenzaldehyde (824-42-0)
• Benzaldehyde, 2-mercapto-3-methyl- (1259480-34-6)

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