Can non-polar hydrogen atoms accept hydrogen bonds???
Chemical Communications Pub Date: 2013-10-22 DOI: 10.1039/C3CC46048G
Abstract
We examine an unusual case where a neutral hydrogen atom acts as a hydrogen-bond acceptor. The association constant between trihexylsilane and perfluoro-tert-butanol was measured as ～0.8 M?1 in cyclohexane. Computations and experimental NMR data are consistent with a weak, but favourable Si–H?HO interaction.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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