Cationic palladium(ii) complexes as catalysts for the oxidation of terminal olefins to methyl ketones using hydrogen peroxide?
Green Chemistry Pub Date: 2015-03-09 DOI: 10.1039/C4GC02465F
Abstract
Ligated Pd(II) complexes have been studied for the catalytic oxidation of terminal olefins to their corresponding methyl ketones. The method uses aqueous hydrogen peroxide as the terminal oxidant; a sustainable and readily accessible oxidant. The choice of ligand, counterion and solvent all have a significant effect on catalytic performance and we were able to develop systems which perform well for these challenging oxidations.
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Journal Name：Green Chemistry
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CAS no.: 89640-58-4
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