Generation and fate of 1-adamantyl-vinyl cations
Journal of the Chemical Society D: Chemical Communications Pub Date: DOI: 10.1039/C29690001349
Abstract
The 1-(1-adamantyl)vinyl cations (II), generated in sulphuric acid either by addition of 1-adamantyl carbonium ions to acetylene or by protonation of 1-adamantylacetylenes (I), are transformed into mixtures of 1-adamantyl methyl ketones (III) and homoadamantan-4-ones (V).
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Journal Name：Journal of the Chemical Society D: Chemical Communications
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CAS no.: 89640-58-4
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