meso- and (±)-Bis(phenylsulphinyl)methane. Characterization using nuclear magnetic resonance chemical shift reagents

Journal of the Chemical Society D: Chemical Communications Pub Date: DOI: 10.1039/C29710001092

Abstract

meso- and (±)-Bis(phenylsulphinyl)methane (II) have been synthesized by oxidation of bis(phenylthio)methane (I) with hydrogen peroxide; structures are assigned to the isomers on the basis of the n.m.r. spectrum in the presence of tris(dipivaloylmethanato)europium.

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