Pyrolysis of disodium perfluoroglutarate and of perfluoroglutaric anhydride over potassium fluoride
Journal of the Chemical Society C: Organic Pub Date: DOI: 10.1039/J39690001331
Abstract
Pyrolysis of disodium perfluoroglutarate gives a complex product containing cis- and trans-perfluorobut-2-enoyl fluoride and perfluorobut-3-enoyl fluoride. Passage of perfluoroglutaric anhydride over potassium fluoride at 420–450° also yields a mixture of these alkenoyl fluorides, which can be converted into mixed sodium perfluorobutenoates that, when pyrolysed, give, inter alia, perfluoro(methylacetylene).
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Journal Name：Journal of the Chemical Society C: Organic
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CAS no.: 89640-58-4
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