Biosynthesis of chimonanthine from [2-3H]tryptophan and [2-3H]tryptamine
Journal of the Chemical Society C: Organic Pub Date: DOI: 10.1039/J39690001916
Abstract
Conversion of (±)-[β-14C, 2-3H]tryptophan and [β-14C, 2-3H]tryptamine into (–)-chimonanthine has been shown to occur in Chimonanthus fragrans(praecox) without loss of tritium. Degradation of the alkaloid has established the predicted labelling pattern. A synthesis of [2-3H]- and [2-3H]-indole from indoxyl is recorded and the structure of diacetoxymercuri-indole is revised.
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Journal Name：Journal of the Chemical Society C: Organic
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CAS no.: 89640-58-4
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