The chemistry of terpenes. Part XI. Volatile products of the photolysis of (+)-cis-caran-5-one
Journal of the Chemical Society C: Organic Pub Date: DOI: 10.1039/J39700001447
Abstract
Irradiation of (+)-cis-caran-5-one in ether, through quartz, affords the following volatile products: (–)-cis-m-menth-8-en-5-one, (–)-cis-m-menthan-5-one, (–)-m-menth-3-en-5-one, (–)-cis-m-menthan-cis-5-ol, (–)-cis-m-menthan-trans-5-ol, and cis-m-menth-8-en-cis-5-ol. In n-hexane, even after considerable periods of irradiation, only the three ketones are formed, and in benzene, (–)-m-menth-3-en-5-one is the sole volatile product.
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Journal Name：Journal of the Chemical Society C: Organic
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CAS no.: 89640-58-4
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