Polar and steric effects in hydrogen abstraction by dialkylamine cation radicals
Journal of the Chemical Society B: Physical Organic Pub Date: DOI: 10.1039/J29680000324
Abstract
The high selectivity observed in the chlorination of methyl decanoate by N-chlorodialkylamines is due to the inductive effect of the methoxycarbonyl group and a (ω– 1) effect which seems to be steric. This second effect occurs also in the chlorination of n-heptane, in which the methylene at position 2 is more reactive than the others, and it is increased by use of an N-chlorodialkylamine with higher steric requirement.
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Journal Name：Journal of the Chemical Society B: Physical Organic
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CAS no.: 89640-58-4
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