The infrared spectra and vibrational assignments of the acetyl halides
Journal of the Chemical Society B: Physical Organic Pub Date: DOI: 10.1039/J29680000118
Abstract
The infrared spectra of acetyl fluoride, acetyl chloride, [2H3]acetyl chloride, acetyl bromide, and acetyl iodide have been obtained in both the liquid and gaseous phase and frequencies have been assigned to the fundamental vibrations. The assignment for acetyl chloride is in close agreement with that of Overend et al.
The low frequency values associated with the carbon–halogen stretching modes and the high ones associated with ν(C![[double bond, length half m-dash]](http://scimg.chem960.com/usr/1/J29680000118.jpg)
O) are attributed mainly to vibrational coupling.
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Journal Name：Journal of the Chemical Society B: Physical Organic
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CAS no.: 89640-58-4
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