Pyrolysis of thio- and isothio-cyanates. Part I. Some simple alkyl isothiocyanates
Journal of the Chemical Society B: Physical Organic Pub Date: DOI: 10.1039/J29690000347
Abstract
The gas-phase decomposition of ethyl, isopropyl, and t-butyl isothiocyanates has been studied in the pressure range of 35–350 mm. The reaction, which has been found to be the unimolecular elimination of thiocyanic acid, is followed by a slow addition of the acid to the olefins to yield mainly the isothiocyanate expected by Markownikoff addition.
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Journal Name：Journal of the Chemical Society B: Physical Organic
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CAS no.: 89640-58-4
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