Co-ordination chemistry of scandium. Part I. Complexes of scandium(III) chloride and thiocyanate with 2,2′-bipyridyl and 1,10-phenanthroline
Journal of the Chemical Society A: Inorganic, Physical, Theoretical Pub Date: DOI: 10.1039/J19690000427
Abstract
The reactions of scandium(III) chloride and thiocyanate with 2,2′-bipyridyl (bipy) and 1,10-phenanthroline (phen) have been investigated. Conductivity and i.r. studies suggest that scandium(III) is hexaco-ordinated in all the complexes, and the products can be formulated as [ScL3](CNS)3 and [ScL2X2]X (L = bipy, phen; X = CNS–, Cl–) For the latter species, the chlorides possess cis(C2) molecular symmetry, while the thiocyantes have been obtained with both cis and trans(D2h) symmetries.
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Journal Name：Journal of the Chemical Society A: Inorganic, Physical, Theoretical
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CAS no.: 89640-58-4
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