LiSb(edta)(H2O): a convenient preserser to LiSbS2 and LiSbO3
Journal of Materials Chemistry Pub Date: DOI: 10.1039/JM9960600789
Abstract
The synthesis and crystal structure of the edta complex LiSb(edta)(H2O) are reported (H4edta = ethylenediaminetetraacetic acid). The compound crystallizes in the monoclinic system. Sb(edta) entities are connected by cyclic [Li(COO)]2 dimers resulting in parallel layers stacked in the [110] direction. Pyrolysis of this complex under sulfur vapour between 700 and 850 °C leads to the mixed sulfide β-LiSbS2. Pyrolysis in air above 660 °C allows the preparation of the mixed oxide LiSbO3.
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Journal Name：Journal of Materials Chemistry
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CAS no.: 89640-58-4
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