Alkali metal carbonate catalyzed copolymerization of anhydrides and epoxides: a simple, efficient and versatile approach to well-defined alternating polyesters?

Polymer Chemistry Pub Date: 2023-03-09 DOI: 10.1039/D2PY01507B

Abstract

Ring-opening alternating copolymerization (ROAC) has recently become an attractive strategy for polyester synthesis. To date, ROAC catalysts have been restricted to organometallics and organic super-bases. In this work, we report ROAC using alkali metal carbonates (AMCs), one of the most common, simple, and inexpensive reagents in the laboratory, as efficient and environmentally benign catalysts. The ROAC of phthalate anhydride (PA) and propylene oxide (PO) can be catalyzed efficiently by AMC at 100 °C to afford polyesters with perfectly alternating structures. The structural and functional diversity of the resultant polyesters can be expanded by using various epoxide monomers and alcohol initiators. An alkali metal cation dissociated from the AMC successively activates the anhydride and the epoxide, and the carbonate anion activates the terminated hydroxyl. The cooperative catalysis accelerates the generation of the alternating structure.

Graphical abstract: Alkali metal carbonate catalyzed copolymerization of anhydrides and epoxides: a simple, efficient and versatile approach to well-defined alternating polyesters
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