NHC–alcohol adduct-mediated photocatalytic deoxygenation for the synthesis of 6-phenanthridine derivatives?
Organic & Biomolecular Chemistry Pub Date: 2022-06-21 DOI: 10.1039/D2OB00814A
Abstract
NHC–alcohol adduct-mediated deoxygenation of alcohols under photocatalytic conditions is described. This process provides various alkyl radicals, which can react with 2-isocyanobiaryls to afford 6-substituted phenanthridine derivatives in moderate to good yields. This method offered the first example of directly using alcohols as radical sources for 6-phenanthridine synthesis.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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