A cis-β-iron(iii) SALPN catalyst for hydrogen atom transfer reductions and olefin cross couplings?

Organic & Biomolecular Chemistry Pub Date: 2023-08-01 DOI: 10.1039/D3OB01085F

Abstract

An inexpensive Fe(III) SALPN catalyst for MHAT reactions such as reductions of α,β-unsaturated carbonyl compounds and olefin cross couplings is reported. The majority of these reactions proceeded in good yields and high stereoselectivities with low catalyst loadings at room temperature.

Graphical abstract: A cis-β-iron(iii) SALPN catalyst for hydrogen atom transfer reductions and olefin cross couplings
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