Copper–cobalt coordination polymers and catalytic applications on borrowing hydrogen reactions?
New Journal of Chemistry Pub Date: 2022-07-04 DOI: 10.1039/D2NJ01763F
Abstract
Porous copper and cobalt polymers were designed, synthesized, and characterized by scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray photoelectron spectrometry (XPS), Fourier-transform infrared (FT-IR) spectroscopy, and X-ray diffraction (XRD). The resulting copper/cobalt composites exhibited a much higher catalytic activity towards the borrowing hydrogen reactions of benzenesulfonamides with benzyl alcohols and carboxamides with alcohols than copper polymers. In addition, copper/cobalt composites could be easily recovered and reused at least six times. Mechanism investigations were conducted to study Cu/Co composites and these transformations.
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Journal Name：New Journal of Chemistry
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CAS no.: 89640-58-4
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