An unprecedented co-crystal including a cis-high-spin and a trans-low-spin FeII complex molecule
Chemical Communications Pub Date: 2007-10-09 DOI: 10.1039/B710734J
Abstract
Two structurally and magnetically nonequivalent isomeric molecules, a cis-high-spin and a trans-low-spin isomer constitute the unit cell of a new iron(II) complex {cis-[FeLB5(NCS)2]·trans-[FeLB5(NCS)2]}·CH3OH, 1, (LB5 = N,N′-bis((2-N-methylimidazol-1-yl)methylene))-2,2-dimethylpropane-1,3-diamine); the synthesis, X-ray structure, and magnetic and M?ssbauer study of this unique example of co-crystallised geometric, conformational and electronic isomers are reported.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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