Two novel metal–organic frameworks constructed by pyridinyl-derived and carboxylate mixed ligands for photocatalytic dye degradation?
New Journal of Chemistry Pub Date: 2023-04-18 DOI: 10.1039/D2NJ05751D
Abstract
A new rigid bipyridinyl-derived ligand has been utilized for the fabrication of two metal–organic frameworks, denoted as [M(L)(mipa)]n [M = Zn (1) and Cd (2), L = 2,6-bis((E)-4-(pyridine-3-yl)benzylidene)cyclohexanone, H2mipa = 5-methylisophthelic acid], through solvothermal synthesis by using a mixed-ligand strategy. Structural analysis reveals that these isomorphic compounds display a 3,5-connected two-dimensional network with an unprecedented (42·67·8)(42·6) topology. Both of them exhibit certain chemical stability and thermal stability. Notably, the photocatalytic properties of the two compounds for the degradation of several organic dyes have been explored.
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Journal Name：New Journal of Chemistry
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CAS no.: 89640-58-4
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