Thermoneutral synthesis of spiro-1,4-cyclohexadienes by visible-light-driven dearomatization of benzylmalonates?
Green Chemistry Pub Date: 2022-02-07 DOI: 10.1039/D1GC04686A
Abstract
A visible-light-driven dearomatization of unactivated arenes with perfect atom economy to access spiro-1,4-cyclohexadienes is disclosed. Calculations suggest that the overall process is approximately thermoneutral, showcasing the special opportunities of light-driven processes to develop sustainable transformations that defy thermodynamic requirements.
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Journal Name：Green Chemistry
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CAS no.: 89640-58-4
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