Cu4Ti4-oxo clusters functionalized by in situ – generated 2,2′-biphenolate ligands from the oxidative coupling of phenols?
Dalton Transactions Pub Date: 2023-01-19 DOI: 10.1039/D2DT03756D
Abstract
Herein, we report a twisted cubic Cu(I)4Ti(IV)4-oxo cluster stabilized by in situ – formed 2,2′-biphenolate ligands from the oxidative coupling of phenols. The 2,2′-biphenolate-functionalized Cu(I)4Ti(IV)4O4 cluster shows short Cu?C contacts and exhibits smaller HOMO–LUMO gaps than those of reported Ti(IV)4O4.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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