Palladium-catalyzed disilylation of ortho-halophenylethylenes enabled by 2-pyridone ligand??
Chemical Communications Pub Date: 2023-04-18 DOI: 10.1039/D3CC01452E
Abstract
A palladium-catalyzed disilylation reaction applicable for a variety of non-, α-, or β-substituted and α,β-disubstituted ortho-halophenylethylenes has been developed. This reaction proceeds with high yields and very low catalyst loadings. The two C–Si bonds of the disilylated products could be well-differentiated chemoselectively in the reaction with various electrophiles.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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