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An efficient cleavage of the aryl ether C–O bond in supercritical carbon dioxide–water?

Chemical Communications Pub Date: 2013-03-28 DOI: 10.1039/C3CC41522H

Abstract

A simple and highly efficient Rh/C catalyzed route for the cleavage of the C–O bond of aromatic ether at 80 °C in the presence of 0.5 MPa of H₂ in the scCO₂–water medium is reported; CO₂ pressure and water play a key role under the tested conditions.

Graphical abstract: An efficient cleavage of the aryl ether C–O bond in supercritical carbon dioxide–water

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