Visible-light-mediated guest trapping in a photosensitizing porous coordination network: metal-free C–C bond-forming modification of metal–organic frameworks for aqueous-phase herbicide adsorption?
Chemical Communications Pub Date: 2019-04-08 DOI: 10.1039/C9CC01371G
Abstract
A series of furan/thiophene-derived Cr-MIL-101s were obtained via visible-light-mediated C–C bond-forming catalysis within photosensitizing porous materials. The guest trapping process was achieved under very mild and metal-free conditions, affording newly functionalized MOFs with more π–π stacking, hydrogen bonding properties and excellent adsorption capacity in removing herbicides from aquatic environments.
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Journal Name:Chemical Communications
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CAS no.: 89640-58-4