Ruthenium(ii)-catalyzed α-fluoroalkenylation of arenes via C–H bond activation and C–F bond cleavage?
Organic Chemistry Frontiers Pub Date: 2018-05-07 DOI: 10.1039/C8QO00297E
Abstract
Ru(II)-Catalyzed efficient α-fluoroalkenylation of arenes has been realized with gem-difluorostyrene as an olefinating reagent. This coupling system is efficient with a broad substrate scope, providing 1,2-diaryl-substituted monofluoroalkenes with good to excellent regio- and stereoselectivities under silver-free conditions.
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Journal Name：Organic Chemistry Frontiers
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