Production of formate from CO2 gas under ambient conditions: towards flow-through enzyme reactors?
Green Chemistry Pub Date: 2020-05-15 DOI: 10.1039/D0GC00952K
Abstract
A flow-through bi-enzymatic reactor was developed to produce formate from carbon dioxide gas (CO2). The reaction operates under ambient conditions without hydrogen gas (H2) and involves a high performance formate dehydrogenase from Methylobacterium extorquens AM1 (MeFoDH1). The tandem reaction features in situ regeneration of the nicotinamide adenine dinucleotide (1,4-NADH) cofactor performed by a highly active mutant of the phosphite dehydrogenase from Pseudomonas stutzeri, without any side reaction. One of the highest turnover numbers reported to date in the literature was reached (6700) giving a high space–time yield of 0.6 mmolformate min?1 L?1reactor.
Recommended Literature
- [1] Estimating and correcting interference fringes in infrared spectra in infrared hyperspectral imaging Ghazal Azarfar,Ebrahim Aboualizadeh,Nicholas M. Walter,Simona Ratti,Camilla Olivieri,Alessandra Norici,Michael Nasse,Achim Kohler,Mario GiordanoAnalyst, 2018,143, 4674-4683 10.1039/C8AN00093J
- [2] Distribution pattern and allocation of defects in hydrogenated ZnO thin films? Vitaly Gurylev,Chung-Yi Su,Tsong-Pyng PerngPhys. Chem. Chem. Phys., 2016,18, 16033-16038 10.1039/C6CP01768A
- [3] Evolved polymerases facilitate selection of fully 2′-OMe-modified aptamers? Zhixia Liu,Tingjian Chen,Floyd E. RomesbergChem. Sci., 2017,8, 8179-8182 10.1039/C7SC03747C
- [4] Enantiomeric helical TiO2 nanofibers modulate different peptide assemblies and subsequent cellular behaviors? Xu Jie,Deng Xu,Weili WeiRSC Adv., 2019,9, 29149-29153 10.1039/C9RA04660G
- [5] Examination of the hydrogen-bonding networks in small water clusters (n = 2–5, 13, 17) using absolutely localized molecular orbital energy decomposition analysis? Erika A. Cobar,Paul R. Horn,Robert G. Bergman,Martin Head-GordonPhys. Chem. Chem. Phys., 2012,14, 15328-15339 10.1039/C2CP42522J
- [6] Exceptionally high temperature spin crossover in amide-functionalised 2,6-bis(pyrazol-1-yl)pyridine iron(ii) complex revealed by variable temperature Raman spectroscopy and single crystal X-ray diffraction? Max Attwood,Hiroki Akutsu,Lee Martin,Toby J. Blundell,Pierre Le Maguere,Scott S. TurnerDalton Trans., 2021,50, 11843-11851 10.1039/D1DT01743H
- [7] Elusive 2-aminofuran Diels–Alder substrates for a straightforward synthesis of polysubstituted anilines? Ana G. Neo,Ana Bornadiego,Jesús Díaz,Stefano Marcaccini,Carlos F. MarcosOrg. Biomol. Chem., 2013,11, 6546-6555 10.1039/C3OB41411F
- [8] Enantiomorphic symmetry breaking in crystallization of molten sodium chlorate? Martin R. Ward,Gary W. Copeland,Andrew J. AlexanderChem. Commun., 2010,46, 7634-7636 10.1039/C0CC02563A
- [9] Distribution and ecological risk assessment of typical antibiotics in the surface waters of seven major rivers, China? Environ. Sci.: Processes Impacts, 2021,23, 1088-1100 10.1039/D1EM00079A
- [10] Emerging investigator series: kinetics of diopside reactivity for carbon mineralization in mafic–ultramafic rocks BrianaAguila,LandonHardee,H.ToddSchaef,SiavashZare,MohammadJavadAbdolhosseiniQomi,JarrodV.Crum,JadeE.HollimanJr.,ElenaTajueloRodriguez,LawrenceM.Anovitz,KevinM.Rosso,QuinR.S.Miller 10.1039/d3en00087g
Journal Name：Green Chemistry
research_products
-
CAS no.: 89640-58-4
![1,2,3,4,5,6-Hexahydro-[2,3]bipyridinyl-6-ol](https://ossimg.kuujia.com/scimg/1271000/1270529-38-8x500.png)
![N-(3-cyanothiolan-3-yl)-2-[(2,2,2-trifluoroethyl)sulfanyl]pyridine-4-carboxamide](https://ossimg.kuujia.com/scimg/1444500/1444113-98-7x500.png)
![2,2-Difluoro-3-[methyl(2-methylbutyl)amino]propanoic acid](https://ossimg.kuujia.com/scimg/2138500/2138166-62-6x500.png)
![2-(1H-indol-3-yl)-N-{[6-(thiophen-2-yl)-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]methyl}acetamide](https://ossimg.kuujia.com/scimg/2034500/2034271-14-0x500.png)