Preservation of epoxy groups on surfaces in the covalent attachment of butadiene monoxide on Si(111)-(7×7): the effect of a vinyl substituent?
Chemical Communications Pub Date: 2015-07-20 DOI: 10.1039/C5CC04713G
Abstract
Adsorption of butadiene monoxide on Si(111)-(7×7) has been scrutinized by high-resolution electron energy loss spectroscopy (HREELS), scanning tunneling microscopy (STM) and density functional theory (DFT) calculations. The experimental results indicate that surface reaction occurs through a [2+2]-like cycloaddition, which is further supported by the DFT studies.
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Journal Name:Chemical Communications
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CAS no.: 89640-58-4