Photocatalytic hydrogen evolution by Cu(ii) complexes?
Dalton Transactions Pub Date: 2016-03-02 DOI: 10.1039/C5DT04628A
Abstract
[Cu(TMPA)Cl]Cl (1) and [Cu(Cl-TMPA)Cl2] (2) exhibited efficient photocatalytic H2 evolution with a TON of 6108 and 10014 (6 h), respectively, in CH3CN/H2O solution (9?:?1, v/v) containing an Ir complex as the photosensitizer and triethylamine as the sacrificial reductant, representing the first example of photocatalytic Cu complex-based water reduction catalysts.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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