Acid-promoted denitrogenative Pd-catalyzed addition of arylhydrazines with nitriles at room temperature?
Organic Chemistry Frontiers Pub Date: 2016-12-13 DOI: 10.1039/C6QO00634E
Abstract
The Pd(TFA)2-catalyzed denitrogenative addition proceeded with selective C–N bond cleavage of arylhydrazines with nitriles in the presence of DABCO and HFBA under air at room temperature. Aryl ketones could be easily synthesized via the hydrolysis of the ketimine moiety generated in situ without the need for additional water.
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Journal Name：Organic Chemistry Frontiers
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CAS no.: 89640-58-4
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