An efficient catalyst-free Mukaiyama-aldol reaction of fluorinated enol silyl ethers with tryptanthrin?
Organic & Biomolecular Chemistry Pub Date: 2015-07-15 DOI: 10.1039/C5OB01125F
Abstract
We report an efficient Mukaiyama-aldol reaction of tryptanthrin with fluorinated enol silyl ethers, which is carried out in methanol without the use of any catalyst. This method is applied to the total synthesis of the difluoro analogues of the natural product Phaitanthrin B.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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