From ethylzinc guanidinate to [Zn10O4]-supertetrahedron?
Dalton Transactions Pub Date: 2017-06-14 DOI: 10.1039/C7DT01619K
Abstract
The controlled hydrolysis of an ethylzinc guanidinate complex affording an alkylzinc cluster containing a [Zn10O4]12+ supertetrahedron core stabilized by the guanidinate ligands is described. Accompanying investigations on the reactivity of this unprecedented cluster toward alcohols resulted in the formation of a mononuclear zinc alkoxide supported by the guanidinate ligands.
![Graphical abstract: From ethylzinc guanidinate to [Zn10O4]-supertetrahedron](http://scimg.chem960.com/usr/1/C7DT01619K.jpg)
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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