Transition metal-free generation of the acceptor/acceptor-carbene via α-elimination: synthesis of fluoroacetyl cyclopropanes?
Chemical Communications Pub Date: 2016-04-22 DOI: 10.1039/C6CC01576J
Abstract
An efficient transition metal-free approach for the generation of acceptor/acceptor-carbene followed by trapping with alkenes to provide fluoroacetyl cyclopropanes has been described. The resulting cyclopropanes could be further converted into the fluoromethyl dihydrofurans or fluorodihydropyrroles through ring-expansion processes.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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