The transition-metal-catalyst-free oxidative homocoupling of organomanganese reagents prepared by the insertion of magnesium into organic halides in the presence of MnCl2·2LiCl?
Organic & Biomolecular Chemistry Pub Date: 2014-08-08 DOI: 10.1039/C4OB01235F
Abstract
Organomanganese reagents were prepared by the insertion of magnesium into aryl halides in the presence of MnCl2·2LiCl. These organomanganese reagents smoothly undergo 1,2-addition, acylation, and Pd-catalyzed cross-coupling with various electrophiles. Especially, the oxidative homocoupling of organomanganese reagents was completed in one pot without an additional transition-metal catalyst.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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