Towards a practical perfluoroalkylation of (hetero)arenes with perfluoroalkyl bromides using cobalt nanocatalysts?
Catalysis Science & Technology Pub Date: 2020-01-28 DOI: 10.1039/C9CY02460C
Abstract
A convenient methodology for perfluoroalkylation including trifluoromethylation of (hetero)arenes with perfluoroalkyl bromides was developed. Key for the success is the use of a specific cobalt-based nanocatalyst, which can be recycled at least up to 4 times. The scope of this first cobalt-catalyzed perfluoroalkylation is presented and detailed catalyst characterization (e.g. analytical STEM, XPS, and XRD) has been carried out.
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Journal Name：Catalysis Science & Technology
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CAS no.: 89640-58-4
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