Synthesis of chiral γ-aminophosphonates through the organocatalytic hydrophosphonylation of azadienes with phosphites?
Organic Chemistry Frontiers Pub Date: 2018-01-29 DOI: 10.1039/C7QO01158J
Abstract
An organocatalytic enantioselective 1,4-addition of phosphites to azadienes has been successfully developed using quinine as a catalyst, providing an efficient and facile route to optically active γ-aminophosphonates with up to 94% ee.
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Journal Name：Organic Chemistry Frontiers
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