Synthesis of ketones by palladium-catalysed desulfitative reaction of arylsulfinic acids with nitriles?

Chemical Communications Pub Date: 2011-07-18 DOI: 10.1039/C1CC13352G

Abstract

Palladium-catalysed desulfitative addition of arylsulfinic acids to aryl and alkyl nitriles with 2,2′-bipyridine as a ligand afforded a variety of aryl ketonesviahydrolysis of ketimine intermediates.

Graphical abstract: Synthesis of ketones by palladium-catalysed desulfitative reaction of arylsulfinic acids with nitriles
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