Zinc and cobalt complexes based on tripodal ligands: synthesis, structure and reactivity toward lactide?
Dalton Transactions Pub Date: 2014-01-06 DOI: 10.1039/C3DT52629A
Abstract
The coordination chemistry of a series of pro-ligands ([L1]–[L6]) with cobalt and zinc derivatives has been studied. All complexes have been characterized by multinuclear NMR, elemental analysis, and by single-crystal X-ray diffraction studies. Polymerization of rac-lactide takes place at 130 °C in the presence of cobalt and zinc complexes to yield polymers under solvent free conditions with controlled molecular masses and narrow polydispersities.
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Journal Name：Dalton Transactions
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